By Lixiong Shao,Jianmei Lu,Min Shi

glossy natural synthesis has paid a lot realization to the chemistry of small carbocycles. Vinylidenecyclopropanes (VDCPs), that have strained cyclopropyl workforce hooked up with an allene moiety and but are thermally sturdy and reactive elements in natural chemistry, are flexible intermediates in natural synthesis. during this quantity, Dr. Lixiong Shao, Dr. Jianmei Lu and Prof. Dr. Min Shi overview their investigations at the chemistry of VDCPs, frequently together with the practise, the reactivities upon remedy with Lewis or Brønsted acid, in addition to transition steel catalysts and a few different miscellaneous analogues. The contributions aroused a renaissance of cationic intermediates within the chemistry of VDCPs.

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