By Arimasa Matsumoto

Iron catalysts in natural synthesis are strongly favorite simply because iron is non-toxic, low-cost and the main plentiful transition steel within the earth, even though their use continues to be restricted in comparison with that of infrequent, useful metals resembling palladium, ruthenium and rhodium. This thesis describes the 1st useful instance of iron catalysis within the carbon–hydrogen bond activation response to synthesized fused fragrant ring compounds. by utilizing a special blend of iron catalyst and dichloride oxidant, a number of type of naphthalene and phenanthrene derivatives have been synthesized through annulation response with alkynes together with direct C–H bond activation strategy. This fulfillment opens the hot threat of low-valent iron catalysis and expands artificial equipment for a sustainable society.

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