By Rui Shang
This thesis provides the most recent advancements in new catalytic C–C bond formation equipment utilizing simply obtainable carboxylate salts via catalytic decarboxylation with stable atom financial system, and utilizing the sustainable aspect iron because the catalyst to at once turn on C–H bonds with excessive step potency. during this regard, it explores a mechanistic figuring out of the newly came upon decarboxylative couplings and the catalytic reactivity of the iron catalyst with the aid of density sensible conception calculation.
The thesis is split into elements, the 1st of which makes a speciality of the improvement of a sequence of formerly unexplored, reasonably cheap carboxylate salts as precious development blocks for the formation of assorted C–C bonds to entry priceless chemical substances. In flip, the second one half is dedicated to a number of new C–C bond formation methodologies utilizing the main ubiquitous transition steel, iron, as a catalyst, and utilizing the ever present C–H bond because the coupling partner.
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